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Ti4O7/g-C3N4 for Visible Light Photocatalytic Oxidation of Hypophosphite: Effect of Mass Ratio of Ti4O7/g-C3N4

Overview of attention for article published in Frontiers in Chemistry, July 2018
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Title
Ti4O7/g-C3N4 for Visible Light Photocatalytic Oxidation of Hypophosphite: Effect of Mass Ratio of Ti4O7/g-C3N4
Published in
Frontiers in Chemistry, July 2018
DOI 10.3389/fchem.2018.00313
Pubmed ID
Authors

Wei Guan, Zhenghua Zhang, Shichao Tian, Jianwei Du

Abstract

Hypophosphite wastewater treatment is still a critical issue in metallurgical processes and the oxidation of hypophosphite to phosphate followed by the precipitation of phosphate is an important strategy for hypophosphite wastewater treatment. Herein, Ti4O7/g-C3N4 photocatalysts with various mass ratios (Ti4O7 (m): g-C3N4 (m) = 0.5, 0.2, 0.1, and 0.05) were synthesized by a hydrolysis method and the effect of the mass ratio of Ti4O7 (m): g-C3N4 (m) on Ti4O7/g-C3N4 visible light photocatalytic oxidation of hypophosphite was evaluated. The as-prepared Ti4O7/g-C3N4 were characterized and confirmed by SEM, XPS, XRD and FTIR. Moreover, the specific surface area and the distribution of pore size of Ti4O7/g-C3N4 was also analyzed. Our results showed that Ti4O7/g-C3N4 exhibited remarkably improved photocatalytic performance on hypophosphite oxidation compared with g-C3N4 and meanwhile 1:2-Ti4O7/g-C3N4 with a mass ratio of 0.5 showed the best photocatalytic performance with the highest oxidation rate constant (17.7-fold and 91.0-fold higher than that of pure g-C3N4 and Ti4O7, respectively). The enhanced performance of photocatalytic oxidation of hypophosphite was ascribed to the heterojunction structure of Ti4O7/g-C3N4 with broader light absorption and significantly enhanced efficiency of the charge carrier (e--h+) generation and separation. Additionally, the generated ·OH and · O 2 - radicals contributed to the hypophosphite oxidation during the photocatalytic system.

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Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 18 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
Unknown 18 100%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 5 28%
Unspecified 3 17%
Student > Postgraduate 1 6%
Lecturer > Senior Lecturer 1 6%
Unknown 8 44%
Readers by discipline Count As %
Unspecified 3 17%
Materials Science 2 11%
Chemistry 2 11%
Business, Management and Accounting 1 6%
Chemical Engineering 1 6%
Other 1 6%
Unknown 8 44%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 1. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 24 July 2018.
All research outputs
#17,985,001
of 23,096,849 outputs
Outputs from Frontiers in Chemistry
#1,751
of 6,040 outputs
Outputs of similar age
#237,313
of 329,806 outputs
Outputs of similar age from Frontiers in Chemistry
#64
of 181 outputs
Altmetric has tracked 23,096,849 research outputs across all sources so far. This one is in the 19th percentile – i.e., 19% of other outputs scored the same or lower than it.
So far Altmetric has tracked 6,040 research outputs from this source. They receive a mean Attention Score of 2.0. This one has gotten more attention than average, scoring higher than 62% of its peers.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 329,806 tracked outputs that were published within six weeks on either side of this one in any source. This one is in the 23rd percentile – i.e., 23% of its contemporaries scored the same or lower than it.
We're also able to compare this research output to 181 others from the same source and published within six weeks on either side of this one. This one has gotten more attention than average, scoring higher than 58% of its contemporaries.